Production of fuel-cell grade hydrogen by sorption enhanced water gas shift reaction using Pd/Ni–Co catalysts

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Production of fuel - cell grade hydrogen by sorption enhanced water gas shift reaction using Pd / Ni - Co catalyst

It has been demonstrated both thermodynamically and experimentally that fuel-cell grade hydrogen can be produced by a one-step sorption enhanced water gas shift (SEWGS) process at about 500 oC, where the water gas shift (WGS) catalyst and the CO2 sorbent are highly integrated. A synthetic CaO-based mixed oxide sorbent was also assessed, which showed a good CO2 capture capacity and stability in ...

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Hydrogen-Etched TiO2−x as Efficient Support of Gold Catalysts for Water–Gas Shift Reaction

Hydrogen-etching technology was used to prepare TiO2−x nanoribbons with abundant stable surface oxygen vacancies. Compared with traditional Au-TiO2, gold supported on hydrogen-etched TiO2−x nanoribbons had been proven to be efficient and stable water–gas shift (WGS) catalysts. The disorder layer and abundant stable surface oxygen vacancies of hydrogen-etched TiO2−x nanoribbons lead to higher mi...

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Water-gas Shift Reaction over Ceria-promoted Pt catalysts

Introduction The fuel processor in which hydrocarbon fuels can be converted into hydrogen has recently attracted much attention as a result of the advancement in the fuel cell technology. In a fuel processor, the water-gas shift (WGS) reaction plays a crucial role in the transformation of CO, a well-known poisonous gas to electrode of fuel cell, into hydrogen through reaction with steam. In WGS...

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Nanostructured Au–ceria is a promising new catalyst for low-temperature water-gas shift (LTS). Preparation, characterization, and catalytic properties of this material are reported in this paper. Gold–ceria was prepared by deposition–precipitation (DP), coprecipitation (CP), and gelation methods. The gold loading was varied between 1 and 8.3 at.%, while lanthanum used as a dopant in ceria, was ...

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ژورنال

عنوان ژورنال: Applied Catalysis B: Environmental

سال: 2014

ISSN: 0926-3373

DOI: 10.1016/j.apcatb.2014.01.002